I learned a technique from America's Test Kitchen years back that involves making large wedges of broccoli (or cauliflower) and I like it a lot. The wedges increase the surface area and you toss the broccoli with olive oil, salt, sugar, pepper (and other stuff if you want), heat the oven to 500 with the pan inside, and then put the wedges on the hot pan. The high heat and small amount of sugar really get a good caramelization on it. I then flip them when they are browned to brown them on both sides and pull out smaller ones so they don't overcook -- or sometimes I really char them. It depends upon how the broccoli cuts up. Just don't crowed the pan as that steaming action will slow things down.
Here is the recipe from ATK.
k.
Published January 1, 2008. From Cook's Illustrated.
WHY THIS RECIPE WORKS:
We wanted a roasted broccoli recipe to add concentrated flavor and
dappled browning to broccoli. We were able to get one by cutting the
broccoli to maximize contact with the baking sheet. Slicing the crown
in half and cutting each half into uniform wedges while cutting the
stalks into rectangular pieces slightly smaller than the more delicate
wedges promoted even cooking and browning, making for a perfect
roasted broccoli recipe. (less)
SERVES 4
Trim away the outer peel from the broccoli stalk, otherwise it will
turn tough when cooked. For Roasted Broccoli with Garlic, stir 1
tablespoon minced garlic into the olive oil before drizzling it over
the broccoli.
INGREDIENTS
1large head broccoli (about 1 3/4 pounds)
3tablespoons extra virgin olive oil
1/2teaspoon table salt
1/2teaspoon sugar
Ground black pepper
Lemon wedges for serving
INSTRUCTIONS
1. Adjust oven rack to lowest position, place large rimmed baking
sheet on rack, and heat oven to 500 degrees. Cut broccoli at juncture
of florets and stems; remove outer peel from stalk. Cut stalk into 2-
to 3-inch lengths and each length into 1/2-inch-thick pieces. Cut
crowns into 4 wedges if 3-4 inches in diameter or 6 wedges if 4-5
inches in diameter. Place broccoli in large bowl; drizzle with oil and
toss well until evenly coated. Sprinkle with salt, sugar, and pepper
to taste and toss to combine.
2. Working quickly, remove baking sheet from oven. Carefully transfer
broccoli to baking sheet and spread into even layer, placing flat
sides down. Return baking sheet to oven and roast until stalks are
well browned and tender and florets are lightly browned, 9 to 11
minutes. Transfer to serving dish and serve immediately with lemon
wedges.
RECIPE TESTING
FLAVOR BOOST FOR BROCCOLI
Tossing the broccoli with a little sugar before roasting helps it
brown more evenly and taste even better.