This is an interesting point. So a high in poly-unsaturated fat oil (like grapeseed) would be better/ideal? Or more of a balanced mono/poly oil like peanut oil?
I had never considered this characteristic of oils when doing an initial seasoning, only that the oil had a suitably high smoke point. I use mainly sunflower for neutral/high heat applications, but this is low in polyunsaturated fat.
I never considered it either until I noticed that the rice bran oil just.... really wasn't getting me the seasoning result I was getting from the oils I had been using before.
Sunflower oil is a bit tricky since there's plenty of different kinds with drastically different fat profiles.
I'm honestly not an expert on the subject; just listened to some experts and did some experimentation.
The rice bran is nice for cooking, deep frying, or stuff you just leave around for a while exactly because it doesn't polymerise and is really stable even when heated. But I guess that's a downside for seasoning since polymerisation is exactly what you're looking for.
Never had any major issues before that apart from flaxseed oil which was flaking like crazy. I think most oils will work fairly well for seasoning, with just a few exceptions on the extreme ends.
Just for the sake of convenience I started seasoning with grapeseed simply because it's 'the other neutral oil' I happen to have because I use it on my cutting boards.